The Difference in Effectiveness of Arabica and Robusta Coffee Grounds as Adsorbent Raw Materials for Reducing COD and TSS Levels in Tapioca Wastewater
DOI:
https://doi.org/10.70182/jca.v3i1.2129Keywords:
spent coffee grounds, Arabica coffee, Robusta coffee, adsorption, tapioca wastewater, chemical oxygen demand, total suspended solidsAbstract
Tapioca wastewater contains high concentrations of organic matter and suspended solids that may adversely affect aquatic environments when discharged without adequate treatment. Initial characterization of the wastewater showed a Chemical Oxygen Demand (COD) concentration of 2,546 mg/L and Total Suspended Solids (TSS) of 406 mg/L, indicating the need for an effective, economical, and environmentally sustainable treatment approach. This study aimed to determine and compare the effectiveness of carbonized Arabica and Robusta spent coffee grounds as adsorbents for reducing COD and TSS concentrations in tapioca wastewater. An experimental batch adsorption system was employed using 16 g of adsorbent per 1 L of wastewater, with contact times of 10, 20, 30, and 40 min and a constant stirring speed of 100 rpm. The spent coffee grounds were carbonized prior to adsorption, and COD and TSS concentrations were measured before and after treatment to determine removal efficiency. The results demonstrated that both Arabica and Robusta coffee-ground adsorbents reduced COD and TSS concentrations, with removal efficiency generally increasing with contact time. At the optimum contact time of 40 min, Arabica coffee-ground adsorbent reduced COD by 6.55%, from 2,546 to 2,379 mg/L, whereas Robusta achieved a 4.59% reduction to 2,429 mg/L. The maximum TSS removal efficiencies were 32.26% for Arabica and 22.66% for Robusta. These findings demonstrate that carbonized Arabica spent coffee grounds exhibited greater adsorption effectiveness than Robusta under the experimental conditions, particularly for TSS removal. Nevertheless, the relatively limited COD removal indicates that further optimization of adsorbent preparation and operating conditions is required before this material can be considered an effective standalone treatment for tapioca wastewater.
Downloads
References
Alcaraz, L., Saquinga, D.N., Alguacil, F.J., Escudero, E., & López, F.A. (2021). Application of activated carbon obtained from spent coffee ground wastes to effective terbium recovery from liquid solutions. Metals, 11(4), 630. https://doi.org/10.3390/met11040630
Aouay, F., Attia, A., et al. (2024). Activated carbon prepared from waste coffee grounds: Characterization and adsorption properties of dyes. Materials, 17(13), 3078. https://doi.org/10.3390/ma17133078
Campbell, R., Xiao, B., & Mangwandi, C. (2024). Production of activated carbon from spent coffee grounds (SCG) for removal of hexavalent chromium from synthetic wastewater solutions. Journal of Environmental Management, 366, 121682. https://doi.org/10.1016/j.jenvman.2024.121682
Chen, W.-H., Du, J.-T., Lee, K.-T., Ong, H.C., Park, Y.-K., & Huang, C.-C. (2021). Pore volume upgrade of biochar from spent coffee grounds by sodium bicarbonate during torrefaction. Chemosphere, 275, 129999. https://doi.org/10.1016/j.chemosphere.2021.129999
Hidayati, SDA, & Damajanti, N. (2021). Reduction of Chemical Oxygen Demand (COD) and Total Suspended Solids (TSS) from wastewater of tapioca plant using aluminum sulfate and poly aluminum chloride (PAC) as a coagulant. Research in Chemical Engineering, 1(1). https://doi.org/10.30595/rice.v1i1.5
Islam, MA, Dada, TK, Parvin, MI, Vuppaladadiyam, AK, Kumar, R., & Antunes, E. (2022). Silver ions and silver nanoparticles removal by coffee derived biochar using a continuous fixed-bed adsorption column. Journal of Water Process Engineering, 48, 102935. https://doi.org/10.1016/j.jwpe.2022.102935
Kang, L.-L., Zeng, Y.-N., Wang, Y.-T., Li, J.-G., Wang, F.-P., Wang, Y.-J., Yu, Q., Wang, X.-M., Ji, R., Gao, D., & Fang, Z. (2022). Removal of pollutants from wastewater using coffee waste as adsorbent: A review. Journal of Water Process Engineering, 49, 103178. https://doi.org/10.1016/j.jwpe.2022.103178
Lee, KT, Cheng, CL, Lee, DS, Chen, WH, Vo, DVN, Ding, L., & Lam, SS (2022). Spent coffee grounds biochar from torrefaction as a potential adsorbent for spilled diesel oil recovery and as an alternative fuel. Energy, 239, 122467. https://doi.org/10.1016/j.energy.2021.122467
Liu, et al. (2024). Spent coffee grounds: Present and future of environmentally friendly applications on industries—A review. Trends in Food Science & Technology, 143, 104312. https://doi.org/10.1016/j.tifs.2023.104312
Milanković, V., Tasić, T., Brković, S., Potkonjak, N., Unterweger, C., Bajuk-Bogdanović, D., Pašti, I., & Lazarević-Pašti, T. (2024). Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study. Journal of Water Process Engineering, 63, 105507. https://doi.org/10.1016/j.jwpe.2024.105507
Nguyen, V.-T., Vo, T.-D.-H., Nguyen, T.-B., Dat, N.D., Huu, B.T., Nguyen, (2022). Adsorption of norfloxacin from aqueous solution on biochar derived from spent coffee ground: Master variables and response surface method optimized adsorption process. Chemosphere, 288, 132577. https://doi.org/10.1016/j.chemosphere.2021.132577
Olanrewaju, et al. (2022). Economic and environmental analysis of waste-based bioenergy integration into industrial cassava starch processes in Africa. Sustainable Production and Consumption, 31, 67–81. https://doi.org/10.1016/j.spc.2022.02.002
Pace, G., Farru, G., Asunis, F., Cappai, G., De Bonis, A., Mascolo, M.C., Caniani, D., Mancini, I.M., Masi, S., & Di Capua, F. (2026). Hydrochar from spent coffee ground as a sustainable adsorbent for dye removal from water: Adsorption characterization and improvement via soft alkaline activation. Biomass, 6(1), 6. https://doi.org/10.3390/biomass6010006
Park, J.-E., et al. (2025). Optimization of activated carbon synthesis from spent coffee grounds for enhanced adsorption performance. Molecules, 30(12), 2557. https://doi.org/10.3390/molecules30122557
Pyrzynska, K. (2026). Spent coffee grounds as an adsorbent material for metal ions. Materials, 19(9), 1720. https://doi.org/10.3390/ma19091720
Quintero-Díaz, J. C., & Gil-Posada, J. O. (2024). Batch and semi-continuous treatment of cassava wastewater using microbial fuel cells and metataxonomic analysis. Bioprocess and Biosystems Engineering, 47, 1057–1070. https://doi.org/10.1007/s00449-024-03025-0
Quyen, V.T., Pham, T.-H., Kim, J., Thanh, D.M., Thang, P.Q., Le, Q.V., Jung, S.H., & Kim, T. (2021). Biosorbent derived from coffee husk for efficient removal of toxic heavy metals from wastewater. Chemosphere, 284, 131312. https://doi.org/10.1016/j.chemosphere.2021.131312
Singh, T.A., Pal, N., Sharma, P., & Passari, A.K. (2023). Spent coffee ground: Transformation from environmental burden into valuable bioactive metabolites. Reviews in Environmental Science and Bio/Technology, 22, 887–898. https://doi.org/10.1007/s11157-023-09669-w
Spent coffee ground biochar for phosphate adsorption in water: Influence of pyrolysis temperature and iron-coating activation method. (2024). Cleaner Engineering and Technology, 23, 100839. https://doi.org/10.1016/j.clet.2024.100839
Trieu, Q. A., Hoang, K. D., & Bui, T. H. (2024). Efficient phosphate adsorption in aqueous solution using nano-zirconia impregnated spent coffee grounds and preliminary application as a slow-release fertilizer. Separation Science and Technology, 59(5), 773–789. https://doi.org/10.1080/01496395.2024.2343850
Yustira, A., Arif, H., Zahedi, Z., & Razi, F. (2025). Influence of activators on spent coffee grounds as biosorbent for chromium. Chemical Industry & Chemical Engineering Quarterly, 31(2), 105–111. https://doi.org
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Bagus Kurniawan Saputra, Atmono, Hardoyo (Author)

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.










